This bugfix brought to you by `go vet`

This change replaces a bit of API surface area (the Sub() method on Muxes) with
a slightly more expressive pattern syntax. I'm mostly doing this because it
seems cleaner: the "*" gets to take on a meaning very similar to what it means
in Sinatra (without growing regexp-like middle-of-a-path globbing, which sounds
terrifying and not particularly useful), and we get to nuke a useless function
from the API.

These were introduced by breaking changes in the following commits:
- aca58b22cf (ValidMethodsKey)
- 386323a6ed (HTTP methods are case sensitive)

Package web will now add a key to the environment when it fails to find a
valid route for the requested method, but when valid routes exist for other
methods.

This allows either the 404 handler or a sufficiently clever middleware layer to
provide support for OPTIONS automatically.